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Aluminium sulfide must be stored in air tight sealed containers or ampoules, as it will hydrolyze in the presence of moisture to release hydrogen sulfide, an extremely toxic and unpleasant gas. Disposal. Aluminium sulfide can be neutralized with hydrogen peroxide or bleach. This oxidizes the aluminium sulfide to aluminium sulfate. References

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Aluminium Sulphate Production Line. Aluminium sulphate is a metallic salt formed for commercial purposes by the action of 98% sulphuric acid on an aluminium source such as bauxite, kaolin, or aluminium oxide or hydroxide. The alum is produced at an Al2O3 content of 14-18% in the form of slabs, lumps or powder.

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Alum (papermaker's alum or aluminum sulfate) was used to precipitate the rosin onto paper, forming an alum/rosin sizing. Aluminum sulfate reacts with water—and produces sulfuric acid—and production of paper on the paper machine demanded additional alum, so papermakers often used the salt in excess.

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A series of experiments was conducted to select the most efficient extractant for removing iron from the aluminum sulfate leach solution. Extractants were contacted with the leach solution in separatory funnels at ambient temperature at a 1:1 phase ratio. Kerosine was used as the diluent in all cases. Table 4 shows the iron extraction in percent.

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